In this article, we demonstrate experimentally and verified numerically the excitation of Berreman modes that propagate in a dielectric film of uniaxial anisotropic nanoporous alumina grown on an aluminium substrate. It is an air-dielectric-metal asymmetric polaritonic system with a real part of the effective permittivity having a value near zero. The modes are excited at a wavelength lower than the epsilon near zero wavelength region. Minimum reflection is observed for the mid-infrared p-polarized light, while maximum reflection is observed for the s-polarized light. The experimental results are numerically reproduced for both p- and s-polarized light and confirm the Berreman modes excitation in the system. At the exciting wavelength, the field is confined in the dielectric region near the air-dielectric interface. The reported system is straightforward and could be easily fabricated over a large scale and is helpful in a variety of mid-infrared applications such as thermal management systems, sensors, passive radiative cooling devices, non-linear applications, and terahertz frequency generation.
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