This paper introduces rigorous mathematical foundations for vanadium dioxide (\ce{VO2})-based reconfigurable intelligent surfaces (RIS) by developing a unified fractional calculus framework that overcomes critical limitations in conventional phase-transition models. We derive: (1) First-principles fractional-order permittivity ($\epsilon_f = \epsilon_\infty + \sigma_0/(i\omega)^\alpha\tau^{1-\alpha}$) from generalized Maxwell's equations, capturing intermediate phase dynamics; (2) Closed-form solutions for maximum phase shift ($\Delta\phi_{\max} > 260^\circ$) and thermal crosstalk suppression (-25 dB at 100$\mu$m spacing) via minimax optimization; (3) A Lévy-stable switching model ($\alpha=0.75$) explaining heavy-tailed transition statistics; and (4) A fundamental bandwidth-density limit ($\rho B \leq c_0^2\eta/4\pi f_c^2\tau_{\text{sw}}$) quantifying RIS capacity bounds. Theoretically validated without fabrication, our framework demonstrates 40$^\circ$ wider phase shift, 48\% faster 99th-percentile switching, and 3$\times$ higher bandwidth density versus conventional designs, providing the complete analytical basis for next-generation 6G metasurfaces.