Valley polarization of graphene via the saddle point

Graphene, and other members of the monolayer Xene family, represent an ideal materials platform for "valleytronics", the control of valley localized charge excitations. The absence of a gap in these semi-metals, however, precludes valley excitation by circularly polarized light pulses, sharply circumscribing the possibility of a lightwave valleytronics in these materials. Here we show that combining a deep ultraviolet linearly polarized light pulse with a THz envelope can induce highly valley polarized states in graphene. This dual frequency lightform operates by (i) the deep ultraviolet pulse activating a selection rule at the M saddle points and (ii) the THz pulse displacing the M point excitation to one of the low-energy K valleys. Employing both tight-binding and state-of-the-art time dependent density functional theory, we show that such a pulse results in a near perfect valley polarized excitation in graphene, thus providing a route via the saddle point to a lightwave valleytronics in the gapless Xene family.